[The New Physics and Its Evolution by Lucien Poincare]@TWC D-Link bookThe New Physics and Its Evolution CHAPTER III 30/48
is not equivalent to heat at 100 deg., that means that we cannot in practice construct an engine which shall transform all this heat into work, or that, for the same cold source, the output is greater when the temperature of the hot source is higher; but if it were possible that this cold source had itself the temperature of absolute zero, the whole heat would reappear in the form of work.
The case here considered is an ideal and extreme case, and we naturally cannot realize it; but this consideration suffices to make it plain that the classification of energies is a little arbitrary and depends more, perhaps, on the conditions in which mankind lives than on the inmost nature of things. In fact, the attempts which have often been made to refer the principle of Carnot to mechanics have not given convincing results.
It has nearly always been necessary to introduce into the attempt some new hypothesis independent of the fundamental hypotheses of ordinary mechanics, and equivalent, in reality, to one of the postulates on which the ordinary exposition of the second law of thermodynamics is founded.
Helmholtz, in a justly celebrated theory, endeavoured to fit the principle of Carnot into the principle of least action; but the difficulties regarding the mechanical interpretation of the irreversibility of physical phenomena remain entire.
Looking at the question, however, from the point of view at which the partisans of the kinetic theories of matter place themselves, the principle is viewed in a new aspect.
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