This is the phenomenon of retrograde condensation.

We may say that the properties of the critical point of a homogeneous substance are, in a way, divided, when it is a question of a binary mixture, between the two points mentioned.
Calculation has enabled M.Van der Waals, by the application of his kinetic theories, and M.Duhem, by means of thermodynamics, to foresee most of the results which have since been verified by experiment.

All these facts have been admirably set forth and systematically co-ordinated by M.Mathias, who, by his own researches, moreover, has made contributions of the highest value to the study of questions regarding the continuity of the liquid and gaseous states.
The further knowledge of critical elements has allowed the laws of corresponding states to be more closely examined in the case of homogeneous substances.

It has shown that, as I have already said, bodies must be arranged in groups, and this fact clearly proves that the properties of a given fluid are not determined by its critical constants alone, and that it is necessary to add to them some other specific parameters; M.Mathias and M.D.Berthelot have indicated some which seem to play a considerable part.
It results also from this that the characteristic equation of a fluid cannot yet be considered perfectly known.

Neither the equation of Van der Waals nor the more complicated formulas which have been proposed by various authors are in perfect conformity with reality.