[The New Physics and Its Evolution by Lucien Poincare]@TWC D-Link book
The New Physics and Its Evolution

CHAPTER IV
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He remarks that, in all its generality, the law may be translated thus: If the isothermal diagrams of two substances be drawn to the same scale, taking as unit of volume and of pressure the values of the critical constants, the two diagrams should coincide; that is to say, their superposition should present the aspect of one diagram appertaining to a single substance.

Further, if we possess the diagrams of two bodies drawn to any scales and referable to any units whatever, as the changes of units mean changes in the scale of the axes, we ought to make one of the diagrams similar to the other by lengthening or shortening it in the direction of one of the axes.

M.Amagat then photographs two isothermal diagrams, leaving one fixed, but arranging the other so that it may be free to turn round each axis of the co-ordinates; and by projecting, by means of a magic lantern, the second on the first, he arrives in certain cases at an almost complete coincidence.
This mechanical means of proof thus dispenses with laborious calculations, but its sensibility is unequally distributed over the different regions of the diagram.

M.Raveau has pointed out an equally simple way of verifying the law, by remarking that if the logarithms of the pressure and volume are taken as co-ordinates, the co-ordinates of two corresponding points differ by two constant quantities, and the corresponding curves are identical.
From these comparisons, and from other important researches, among which should be particularly mentioned those of Mr S.Young and M.
Mathias, it results that the laws of corresponding states have not, unfortunately, the degree of generality which we at first attributed to them, but that they are satisfactory when applied to certain groups of bodies.[7] [Footnote 7: Mr Preston thus puts it: "The law [of corresponding states] seems to be not quite, but very nearly true for these substances [_i.e._ the halogen derivatives of benzene]; but in the case of the other substances examined, the majority of these generalizations were either only roughly true or altogether departed from" (_Theory of Heat_, London, 1904, p.

514.)--ED.] If in the study of the statics of a simple fluid the experimental results are already complex, we ought to expect much greater difficulties when we come to deal with mixtures; still the problem has been approached, and many points are already cleared up.
Mixed fluids may first of all be regarded as composed of a large number of invariable particles.


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