[The New Physics and Its Evolution by Lucien Poincare]@TWC D-Link bookThe New Physics and Its Evolution CHAPTER V 13/28
It may be purely fortuitous, but we can hardly refrain from finding in it a physical meaning. Professor Van t'Hoff has considered this coincidence a demonstration that there exists a strong analogy between a body in solution and a gas; as a matter of fact, it may seem that, in a solution, the distance between the molecules becomes comparable to the molecular distances met with in gases, and that the molecule acquires the same degree of liberty and the same simplicity in both phenomena.
In that case it seems probable that solutions will be subject to laws independent of the chemical nature of the dissolved molecule and comparable to the laws governing gases, while if we adopt the kinetic image for the gas, we shall be led to represent to ourselves in a similar way the phenomena which manifest themselves in a solution. Osmotic pressure will then appear to be due to the shock of the dissolved molecules against the membrane.
It will come from one side of this partition to superpose itself on the hydrostatic pressure, which latter must have the same value on both sides. The analogy with a perfect gas naturally becomes much greater as the solution becomes more diluted.
It then imitates gas in some other properties; the internal work of the variation of volume is nil, and the specific heat is only a function of the temperature.
A solution which is diluted by a reversible method is cooled like a gas which expands adiabatically.[17] [Footnote 17: That is, without receiving or emitting any heat .-- ED.] It must, however, be acknowledged that, in other points, the analogy is much less perfect.
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