[The New Physics and Its Evolution by Lucien Poincare]@TWC D-Link bookThe New Physics and Its Evolution CHAPTER V 24/28
The laws of cryoscopy, of tonometry, and of osmosis thus again become strict, and no exception to them remains. If the dissociation of salts is a reality and is complete in a dilute solution, any of the properties of a saline solution whatever should be represented numerically as the sum of three values, of which one concerns the positive ion, a second the negative ion, and the third the solvent.
The properties of the solutions would then be what are called additive properties.
Numerous verifications may be attempted by very different roads.
They generally succeed very well; and whether we measure the electric conductivity, the density, the specific heats, the index of refraction, the power of rotatory polarization, the colour, or the absorption spectrum, the additive property will everywhere be found in the solution. The hypothesis, so contested at the outset by the chemists, is, moreover, assuring its triumph by important conquests in the domain of chemistry itself.
It permits us to give a vivid explanation of chemical reaction, and for the old motto of the chemists, "Corpora non agunt, nisi soluta," it substitutes a modern one, "It is especially the ions which react." Thus, for example, all salts of iron, which contain iron in the state of ions, give similar reactions; but salts such as ferrocyanide of potassium, in which iron does not play the part of an ion, never give the characteristic reactions of iron. Professor Ostwald and his pupils have drawn from the hypothesis of Arrhenius manifold consequences which have been the cause of considerable progress in physical chemistry.
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