[The New Physics and Its Evolution by Lucien Poincare]@TWC D-Link bookThe New Physics and Its Evolution CHAPTER V 8/28
It was interesting to try to reproduce artificially semi-permeable walls analogous to those thus met with in nature;[15] and Traube and Pfeffer seem to have succeeded in one particular case.
Traube has pointed out that the very delicate membrane of ferrocyanide of potassium which is obtained with some difficulty by exposing it to the reaction of sulphate of copper, is permeable to water, but will not permit the passage of the majority of salts.
Pfeffer, by producing these walls in the interstices of a porous porcelain, has succeeded in giving them sufficient rigidity to allow measurements to be made.
It must be allowed that, unfortunately, no physicist or chemist has been as lucky as these two botanists; and the attempts to reproduce semi-permeable walls completely answering to the definition, have never given but mediocre results.
If, however, the experimental difficulty has not been overcome in an entirely satisfactory manner, it at least appears very probable that such walls may nevertheless exist.[16] [Footnote 15: See next note .-- ED.] [Footnote 16: M.Stephane Leduc, Professor of Biology of Nantes, has made many experiments in this connection, and the artificial cells exhibited by him to the Association francaise pour l'avancement des Sciences, at their meeting at Grenoble in 1904 and reproduced in their "Actes," are particularly noteworthy .-- ED.] Nevertheless, in the case of gases, there exists an excellent example of a semi-permeable wall, and a partition of platinum brought to a higher than red heat is, as shown by M.Villard in some ingenious experiments, completely impermeable to air, and very permeable, on the contrary, to hydrogen.
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